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Amphiphilic block copolymer nano-fibers via RAFT-mediated polymerization in aqueous dispersed system. 2010
Stéphanie Boissé, and
Jutta Rieger, and
Khaled Belal, and
Aurélie Di-Cicco, and
Patricia Beaunier, and
Min-Hui Li, and
Bernadette Charleux
UPMC Univ. Paris 6 and CNRS, Laboratoire de Chimie des Polymères, UMR 7610, 4 place Jussieu, Tour 44-54, 75252 Paris cedex 05, France.
Self-assembled block copolymer nanofibers are attractive materials for multiple applications. We propose here a novel, very simple and straightforward method to prepare polymeric nanofibers at high solids contents directly in water. It is based on an aqueous emulsion polymerization process performed under living radical polymerization conditions, using the RAFT method.
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