Palladium-catalyzed cross-coupling reactions of organogold(I) reagents with organic electrophiles. 2010

Miguel Peña-López, and Miguel Ayán-Varela, and Luis A Sarandeses, and José Pérez Sestelo
Departamento de Química Fundamental, Universidade da Coruña, Facultade de Ciencias, A Zapateira, s/n, Spain.

The palladium-catalyzed cross-coupling reaction of organogold(I) reagents (alkyl, alkenyl, aryl, and alkynyl) with organic electrophiles, such as aryl and alkenyl halides, aryl triflates, benzyl bromide, and benzoyl chloride is reported. The reaction takes place, under palladium catalysis, at room temperature with short reaction times to give the corresponding cross-coupling products in high yields.

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