One-pot hydrothermal synthesis of silver nanowires via citrate reduction. 2010

Zhiqiang Yang, and Haijun Qian, and Hongyu Chen, and Jeffrey N Anker
Department of Chemistry, Centre for Optical Materials Research (COMSET), and Environmental Toxicology Program, Hunter Laboratories, Clemson University, Clemson, SC 29634, USA.

We report a novel and simple hydrothermal method to synthesize silver nanowires using only silver nitrate and sodium citrate without any external seeds or templates. The effects of the molar ratio of silver ions to citrate, pH, and the reaction temperature were investigated. Silver nanowires and particles were characterized using scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), powder X-ray diffraction (XRD), and UV/vis absorption spectroscopy. A high yield of nanowires (average diameter 53 ± 4 nm, length up to 6 μm) was obtained under optimized conditions with 1:1 M ratio of Ag(+) to citrate and pH 7.1 (no NaOH added) at 130 °C. Increasing the citrate ratio, increasing the pH with NaOH, or decreasing the reaction temperature all resulted in samples with shorter lengths and fewer nanowires compared to nanospheres. At pH 10.1, monodispersed nanospheres with diameter of 58 ± 9 nm were produced. The nanowire and nanosphere synthetic methods are attractive because of their simplicity, the lack of capping agents besides citrate, and the uniformity of the particles produced.

UI MeSH Term Description Entries
D010084 Oxidation-Reduction A chemical reaction in which an electron is transferred from one molecule to another. The electron-donating molecule is the reducing agent or reductant; the electron-accepting molecule is the oxidizing agent or oxidant. Reducing and oxidizing agents function as conjugate reductant-oxidant pairs or redox pairs (Lehninger, Principles of Biochemistry, 1982, p471). Redox,Oxidation Reduction
D010316 Particle Size Relating to the size of solids. Particle Sizes,Size, Particle,Sizes, Particle
D012834 Silver An element with the atomic symbol Ag, atomic number 47, and atomic weight 107.87. It is a soft metal that is used medically in surgical instruments, dental prostheses, and alloys. Long-continued use of silver salts can lead to a form of poisoning known as ARGYRIA.
D013499 Surface Properties Characteristics or attributes of the outer boundaries of objects, including molecules. Properties, Surface,Property, Surface,Surface Property
D013696 Temperature The property of objects that determines the direction of heat flow when they are placed in direct thermal contact. The temperature is the energy of microscopic motions (vibrational and translational) of the particles of atoms. Temperatures
D053770 Nanowires Nanometer-scale wires made of materials that conduct electricity. They can be coated with molecules such as antibodies that will bind to proteins and other substances. Nanowire
D019343 Citric Acid A key intermediate in metabolism. It is an acid compound found in citrus fruits. The salts of citric acid (citrates) can be used as anticoagulants due to their calcium chelating ability. Citrate,Anhydrous Citric Acid,Citric Acid Monohydrate,Citric Acid, Anhydrous,Uralyt U

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