Secondary organic aerosol from ozonolysis of biogenic volatile organic compounds: chamber studies of particle and reactive oxygen species formation. 2011

Xi Chen, and Philip K Hopke, and William P L Carter
Center for Air Resources Engineering and Science, Clarkson University, Potsdam, New York 13699-5708, USA.

The formation of secondary organic aerosol (SOA) produced from α-pinene, linalool, and limonene by ozonolysis was examined using a dynamic chamber system that allowed the simulation of ventilated indoor environments. Experiments were conducted at typical room temperatures and air exchange rates. Limonene ozonolysis produced the highest SOA mass concentrations and linalool the lowest with α-pinene being intermediate. Simplified empirical modeling simulations were conducted to provide insights into reaction chemistry. Assessment of variability of particle-bound reactive oxygen species (ROS) may be important in the understanding of health effects associated with particulate matter. The ROS intensities defined as ROS/SOA mass were found to be moderately correlated with the SOA densities. Greater ROS intensities were observed for the cases where ozone was in excess. ROS intensities approached a relatively constant value in the region where ozone was in deficit. The estimated initial ROS half-life time was approximately 6.5 h at room temperature suggesting the time sensitivity of ROS measurements. The ROS formed from terpenoid ozonolysis could be separated into three categories: short-lived/high reactive/volatile, semivolatile/relatively stable and nonvolatile/low reactive species based on ROS measurements under various conditions. Such physical characterization of the ROS in terms of reactivity and volatility provides some insights into the nature of ROS.

UI MeSH Term Description Entries
D010126 Ozone The unstable triatomic form of oxygen, O3. It is a powerful oxidant that is produced for various chemical and industrial uses. Its production is also catalyzed in the ATMOSPHERE by ULTRAVIOLET RAY irradiation of oxygen or other ozone precursors such as VOLATILE ORGANIC COMPOUNDS and NITROGEN OXIDES. About 90% of the ozone in the atmosphere exists in the stratosphere (STRATOSPHERIC OZONE). Ground Level Ozone,Low Level Ozone,Tropospheric Ozone,Level Ozone, Ground,Level Ozone, Low,Ozone, Ground Level,Ozone, Low Level,Ozone, Tropospheric
D010316 Particle Size Relating to the size of solids. Particle Sizes,Size, Particle,Sizes, Particle
D000077222 Limonene A naturally-occurring class of MONOTERPENES which occur as a clear colorless liquid at room temperature. Limonene is the major component in the oil of oranges which has many uses, including as flavor and fragrance. It is recognized as safe in food by the Food and Drug Administration (FDA). (+)-(R)-4-isopropenyl-1-methylcyclohexene,(+)-Limonene,(-)-Limonene,(4R)-1-methyl-4-(1-methylethenyl)cyclohexene,(4S)-1-methyl-4-isopropenylcyclohex-1-ene,(D)-Limonene,(R)-(+)-Limonene,(R)-4-isopropenyl-1-methylcyclohexene,1-Methyl-4-(1-methylethenyl)cyclohexene,4-Mentha-1,8-diene,AISA 5203-L (+)Limonene,Cyclohexene, 1-methyl-4-(1-methylethenyl)-, (4R)-,Dipentene,Limonene, (+)-,Limonene, (+-)-,Limonene, (+-)-isomer,Limonene, (R)-isomer,Limonene, (S)-isomer,d-Limonene,4 Mentha 1,8 diene,d Limonene
D000080462 Acyclic Monoterpenes Linear compounds that contain a single monoterpene unit. Monoterpenes, Acyclic
D000081008 Bicyclic Monoterpenes Monoterpenes containing two ring structures that are joined either by bridgehead carbon atoms or fused ring structure. Camphene Derivatives,Camphenes,Carane Derivatives,Caranes,Pinane Derivatives,Pinanes,Thujane Derivatives,Thujanes,Derivatives, Camphene,Derivatives, Carane,Derivatives, Pinane,Derivatives, Thujane,Monoterpenes, Bicyclic
D000336 Aerosols Colloids with a gaseous dispersing phase and either liquid (fog) or solid (smoke) dispersed phase; used in fumigation or in inhalation therapy; may contain propellant agents. Aerosol
D000393 Air Pollutants Any substance in the air which could, if present in high enough concentration, harm humans, animals, vegetation or materials. Substances include GASES; PARTICULATE MATTER; and volatile ORGANIC CHEMICALS. Air Pollutant,Air Pollutants, Environmental,Environmental Air Pollutants,Environmental Pollutants, Air,Air Environmental Pollutants,Pollutant, Air,Pollutants, Air,Pollutants, Air Environmental,Pollutants, Environmental Air
D013729 Terpenes A class of compounds composed of repeating 5-carbon units of HEMITERPENES. Isoprenoid,Terpene,Terpenoid,Isoprenoids,Terpenoids
D016902 Air Pollution, Indoor The contamination of indoor air. Air Quality, Indoor,Indoor Air Pollution,Indoor Air Quality,Pollution, Indoor Air
D017382 Reactive Oxygen Species Molecules or ions formed by the incomplete one-electron reduction of oxygen. These reactive oxygen intermediates include SINGLET OXYGEN; SUPEROXIDES; PEROXIDES; HYDROXYL RADICAL; and HYPOCHLOROUS ACID. They contribute to the microbicidal activity of PHAGOCYTES, regulation of SIGNAL TRANSDUCTION and GENE EXPRESSION, and the oxidative damage to NUCLEIC ACIDS; PROTEINS; and LIPIDS. Active Oxygen Species,Oxygen Radical,Oxygen Radicals,Pro-Oxidant,Reactive Oxygen Intermediates,Active Oxygen,Oxygen Species, Reactive,Pro-Oxidants,Oxygen, Active,Pro Oxidant,Pro Oxidants,Radical, Oxygen

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