2-(4-Methyl-sulfanylphen-yl)-1H-benzimidazol-3-ium bromide. 2011

Mohamed Ziaulla, and M N Manjunatha, and Ravish Sankolli, and K R Nagasundara, and Noor Shahina Begum

In the cation of the title compound, C(14)H(13)N(2)S(+)·Br(-), the essentially planar benzimidazole system (r.m.s. deviation = 0.0082 Å) is substituted with a 4-methyl-sulfanylphenyl ring. The dihedral angle between the benzimidazole system and the 4-methyl-sulfanylphenyl ring is 2.133 (2)°. The crystal structure is characterized by strong and highly directional inter-molecular N-H⋯Br hydrogen bonds involving the bromide ion. Moreover, C-H⋯S inter-actions result in chains of mol-ecules along the c axis. The supra-molecular assembly is further stabilized by π-π stacking inter-actions between the benzimidazole system and 4-methyl-sulfanylphenyl rings [centroid-centroid distance = 3.477 (4) Å].

UI MeSH Term Description Entries

Related Publications

Mohamed Ziaulla, and M N Manjunatha, and Ravish Sankolli, and K R Nagasundara, and Noor Shahina Begum
February 2001, Acta crystallographica. Section C, Crystal structure communications,
Mohamed Ziaulla, and M N Manjunatha, and Ravish Sankolli, and K R Nagasundara, and Noor Shahina Begum
January 2015, Acta crystallographica. Section E, Crystallographic communications,
Mohamed Ziaulla, and M N Manjunatha, and Ravish Sankolli, and K R Nagasundara, and Noor Shahina Begum
December 2007, Acta crystallographica. Section E, Structure reports online,
Mohamed Ziaulla, and M N Manjunatha, and Ravish Sankolli, and K R Nagasundara, and Noor Shahina Begum
December 2022, IUCrData,
Mohamed Ziaulla, and M N Manjunatha, and Ravish Sankolli, and K R Nagasundara, and Noor Shahina Begum
November 2011, Acta crystallographica. Section E, Structure reports online,
Mohamed Ziaulla, and M N Manjunatha, and Ravish Sankolli, and K R Nagasundara, and Noor Shahina Begum
April 2012, Acta crystallographica. Section E, Structure reports online,
Mohamed Ziaulla, and M N Manjunatha, and Ravish Sankolli, and K R Nagasundara, and Noor Shahina Begum
October 2011, Acta crystallographica. Section E, Structure reports online,
Mohamed Ziaulla, and M N Manjunatha, and Ravish Sankolli, and K R Nagasundara, and Noor Shahina Begum
July 2011, Acta crystallographica. Section E, Structure reports online,
Mohamed Ziaulla, and M N Manjunatha, and Ravish Sankolli, and K R Nagasundara, and Noor Shahina Begum
January 2013, Acta crystallographica. Section E, Structure reports online,
Mohamed Ziaulla, and M N Manjunatha, and Ravish Sankolli, and K R Nagasundara, and Noor Shahina Begum
July 2011, Acta crystallographica. Section E, Structure reports online,
Copied contents to your clipboard!