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First enantioselective iron-porphyrin-catalyzed sulfide oxidation with aqueous hydrogen peroxide. 2011

Paul Le Maux, and Gérard Simonneaux
Ingénierie Chimique et Molécules pour le Vivant, UMR CNRS 6226, Campus de Beaulieu, Université de Rennes 1, 35042 Rennes, France.

The asymmetric oxidation of sulfides by H(2)O(2) to give optically active sulfoxides (ee up to 90%) was carried out in methanol and water using chiral water-soluble iron porphyrins as catalysts.

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