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[(Z)-1-Amino-2-cyano-2-(4,6-di-2-pyridyl-pyrimidin-2-yl)ethenolato]chlorido(N,N-dimethyl-formamide-κO)zinc(II). 2010

Fangfang Jian, and Mei Du
New Materials & Function Coordination Chemistry Laboratory, Qingdao University of Science & Technology, Qingdao 266042, People's Republic of China.

In the title complex, [Zn(C(17)H(11)N(6)O)Cl(C(3)H(7)NO)], the Zn(II) atom has a distorted square-pyramidal coordination formed by one Cl, two O and two N atoms. In the crystal structure, inter-molecular N-H⋯Cl hydrogen bonds link mol-ecules into centrosymmetric dimers, which are further assembled by π-π inter-actions [centroid-centroid distances = 3.809 (3) and 3.834 (3) Å] into layers parallel to the ab plane. The crystal packing exhibits also weak inter-molecular C-H⋯Cl inter-actions.

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