2-p-Tolyl-1-p-tolyl-methyl-1H-benzimidazole. 2009

Ting Liu
Biology and Chemistry Department, Nanchang University College of Science and Technology, Nanchang 330029, People's Republic of China.

The asymmetric unit of the title compound, C(22)H(20)N(2), contains two crystallographically independent mol-ecules in which the planar benzimidazole ring systems are oriented with respect to the adjacent tolyl rings at dihedral angles of 47.08 (8)/76.85 (8) and 39.52 (9)/87.49 (9)°, while the dihedral angles between the tolyl rings are 73.99 (3) and 81.51 (9)°. In the crystal structure, pairs of inter-molecular C-H⋯N inter-actions link one of the asymmetric mol-ecules into centrosymmetric dimers through R(2) (2)(8) ring motifs.

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