BIOMAT Database Logo BIOMAT Database Logo

(5S,6R)-5-Methyl-6-phenyl-4-propyl-1,3,4-oxadiazinane-2-thione. 2009

Joshua L Kocher, and Kate L Edler, and Barbara A Bohling, and George P Nora, and Carrie Stafford, and Shawn R Hitchcock, and Gregory M Ferrence
CB 4160, Department of Chemistry, Illinois State University, Normal, IL 61790, USA.

The title mol-ecule, C(13)H(18)N(2)OS, is an oxadiazinanthione derived from (1R,2S)-norephedrine. There are two molecules in the asymmetric. Both adopt roughly half-chair conformations; however, the 5-position carbon orients out of opposite faces of the oxadiazinanthiones plane in the two molecules. In the crystal structure, they are oriented as a dimer linked by a pair of N-H⋯S hydrogen bonds. The absolute configuration has been established from anomalous dispersion and confirms the known stereochemistry based on the synthetic procedure.

UI MeSH Term Description Entries

Related Publications

Joshua L Kocher, and Kate L Edler, and Barbara A Bohling, and George P Nora, and Carrie Stafford, and Shawn R Hitchcock, and Gregory M Ferrence
(6R)-2-tert-Butyl-6-[(4R,5S)-3-isopropyl-4-methyl-5-phenyl-oxazolidin-2-yl]phenol.
March 2010, Acta crystallographica. Section E, Structure reports online,
Joshua L Kocher, and Kate L Edler, and Barbara A Bohling, and George P Nora, and Carrie Stafford, and Shawn R Hitchcock, and Gregory M Ferrence
(5S*,6R*,7R*)-6-Formyl-5-phenyl-7-propyl-perhydro-pyrazolo[1,2-a]pyrazol-1-one.
June 2010, Acta crystallographica. Section E, Structure reports online,
Joshua L Kocher, and Kate L Edler, and Barbara A Bohling, and George P Nora, and Carrie Stafford, and Shawn R Hitchcock, and Gregory M Ferrence
4-Meth-oxy-4-methyl-6-phenyl-1,3-diazinane-2-thione.
December 2012, Acta crystallographica. Section E, Structure reports online,
Joshua L Kocher, and Kate L Edler, and Barbara A Bohling, and George P Nora, and Carrie Stafford, and Shawn R Hitchcock, and Gregory M Ferrence
(5S,6S)-4,5-Dimethyl-3-methyl-acryloyl-6-phenyl-1,3,4-oxadiazinan-2-one.
May 2008, Acta crystallographica. Section E, Structure reports online,
Joshua L Kocher, and Kate L Edler, and Barbara A Bohling, and George P Nora, and Carrie Stafford, and Shawn R Hitchcock, and Gregory M Ferrence
(4S,5S)-4-methyl-5-phenyl-1,3-oxazolidin-2-one.
June 1993, Acta crystallographica. Section C, Crystal structure communications,
Joshua L Kocher, and Kate L Edler, and Barbara A Bohling, and George P Nora, and Carrie Stafford, and Shawn R Hitchcock, and Gregory M Ferrence
(5S,6R)-6-Bromo-6-methyl-5-phenyl-3,4,5,6-tetra-hydro-2H-cyclo-penta-[b]pyran-7-one.
October 2011, Acta crystallographica. Section E, Structure reports online,
Joshua L Kocher, and Kate L Edler, and Barbara A Bohling, and George P Nora, and Carrie Stafford, and Shawn R Hitchcock, and Gregory M Ferrence
(5R,6S)-4-Isopropyl-5-methyl-6-phenyl-3-propanoyl-2H-1,3,4-oxadiazinan-2-one.
June 2009, Acta crystallographica. Section E, Structure reports online,
Joshua L Kocher, and Kate L Edler, and Barbara A Bohling, and George P Nora, and Carrie Stafford, and Shawn R Hitchcock, and Gregory M Ferrence
3-Methyl-5-methyl-sulfanyl-1,3,4-thia-diazole-2(3H)-thione.
October 2012, Acta crystallographica. Section E, Structure reports online,
Joshua L Kocher, and Kate L Edler, and Barbara A Bohling, and George P Nora, and Carrie Stafford, and Shawn R Hitchcock, and Gregory M Ferrence
4-Methyl-N-(2-phenyl-eth-yl)-2-propyl-1H-benzimidazole-6-carboxamide.
October 2012, Acta crystallographica. Section E, Structure reports online,
Joshua L Kocher, and Kate L Edler, and Barbara A Bohling, and George P Nora, and Carrie Stafford, and Shawn R Hitchcock, and Gregory M Ferrence
4-Methyl-3-(2-phenoxy-acet-yl)-5-phenyl-1,3,4-oxadiazinan-2-one.
June 2009, Acta crystallographica. Section E, Structure reports online,
Copied contents to your clipboard!