(S)-6-{[(S)-2,2-Dimethyl-1,3-dioxolan-4-yl]meth-yl}-5,5-difluoro-5,6-dihydro-2H-pyran-2-one. 2009

Zengsheng Yin, and Xiangjun Deng, and Rongxing Yao, and Hongqi Li, and Pinqiao Zhao

The title compound, C(11)H(14)F(2)O(4), is a γ,γ-gem-difluorinated α,β-unsaturated δ-lactone. The dioxolane five-membered ring and the lactone ring adopt half-chair conformations. There are two inter-molecular C-H⋯O inter-actions involving the carbonyl group as an acceptor which stabilize the crystal structure.

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