4-Ethyl-1-[4-(methyl-sulfan-yl)benzyl-idene]thio-semicarbazide. 2010

Yu-Feng Li, and Fang-Fang Jian

There are four independent mol-ecules in the asymmetric unit of the title compound, C(11)H(15)N(3)S(2), with different conformations: the dihedral angles between the benzene rings and thio-urea units are 16.85 (9), 0.56 (10), 8.05 (12) and 4.56 (8)°. Each mol-ecule contains an intra-molecular N-H⋯N hydrogen bond, generating an S(5) ring. The crystal structure is stabilized by inter-molecular N-H⋯S hydrogen bonds.

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