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N-(4-Chloro-phen-yl)-4-methyl-pyridin-2-amine. 2010

Zainal A Fairuz, and Zaharah Aiyub, and Zanariah Abdullah, and Seik Weng Ng, and Edward R T Tiekink
Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.

In the title compound, C(12)H(11)ClN(2), the dihedral angle between the benzene and pyridyl rings is 48.03 (8)°. Twists are also evident in the mol-ecule, in particular about the N(a)-C(b) (a = amine and b = benzene) bond [C-N-C-C = -144.79 (18)°]. In the crystal, inversion dimers linked by pairs of N-H⋯N hydrogen bonds result in the formation of eight-membered {⋯NCNH}(2) synthons [or R(2) (2)(8) loops].

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