N-[(1S,2S)-2-Amino-1,2-diphenyl-eth-yl]-4-methyl-benzene-sulfonamide [(S,S)-TsDPEN]. 2010

Claudine Schlemmer, and Dieter Schollmeyer, and Nancy Blank, and Alexander Stoye, and Till Opatz
Institut für Organische Chemie, Universität Mainz, Duesbergweg 10-14, 55128 Mainz, Germany.

The crystal structure of the title compound, C(21)H(22)N(2)O(2)S, shows a network of N-H⋯N and N-H⋯O hydrogen bonds. The tolyl and 1-phenyl rings are almost mutually coplanar [7.89 (9)°], while the 2-phenyl ring makes a dihedral angle of 50.8 (1) ° with the 1-phenyl ring. An intra-molecular N-H⋯N hydrogen bond stabilizes the mol-ecular conformation.

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