Bis(2-amino-1,3-benzothia-zol-3-ium) tetra-chloridozincate(II). 2011

Riadh Kefi, and Erwann Jeanneau, and Frédéric Lefebvre, and Cherif Ben Nasr

The asymmetric unit of the title compound, (C(7)H(7)N(2)S)(2)[ZnCl(4)], contains a network of 2-amino-benzothia-zolium cations and tetra-hedral [ZnCl(4)](2-) anions. The crystal packing is influenced by cation-to-anion N-H⋯Cl and C-H⋯Cl hydrogen bonds. The [ZnCl(4)](2-) anions have a distorded tetra-hedral geometry. Inter-molecular π-π stacking inter-actions are present between neighboring benzene rings, thia-zole and benzene rings and neighboring thia-zole rings [centroid-centroid distances = 3.711 (2), 3.554 (1), 3.536 (2) and 3.572 (1) Å].

UI MeSH Term Description Entries

Related Publications

Riadh Kefi, and Erwann Jeanneau, and Frédéric Lefebvre, and Cherif Ben Nasr
July 2010, Acta crystallographica. Section E, Structure reports online,
Riadh Kefi, and Erwann Jeanneau, and Frédéric Lefebvre, and Cherif Ben Nasr
August 2014, Acta crystallographica. Section E, Structure reports online,
Riadh Kefi, and Erwann Jeanneau, and Frédéric Lefebvre, and Cherif Ben Nasr
August 2011, Acta crystallographica. Section E, Structure reports online,
Riadh Kefi, and Erwann Jeanneau, and Frédéric Lefebvre, and Cherif Ben Nasr
June 2012, Acta crystallographica. Section E, Structure reports online,
Riadh Kefi, and Erwann Jeanneau, and Frédéric Lefebvre, and Cherif Ben Nasr
September 2017, Acta crystallographica. Section E, Crystallographic communications,
Riadh Kefi, and Erwann Jeanneau, and Frédéric Lefebvre, and Cherif Ben Nasr
November 2011, Acta crystallographica. Section E, Structure reports online,
Riadh Kefi, and Erwann Jeanneau, and Frédéric Lefebvre, and Cherif Ben Nasr
July 2011, Acta crystallographica. Section E, Structure reports online,
Riadh Kefi, and Erwann Jeanneau, and Frédéric Lefebvre, and Cherif Ben Nasr
December 2008, Acta crystallographica. Section E, Structure reports online,
Riadh Kefi, and Erwann Jeanneau, and Frédéric Lefebvre, and Cherif Ben Nasr
November 2010, Acta crystallographica. Section E, Structure reports online,
Riadh Kefi, and Erwann Jeanneau, and Frédéric Lefebvre, and Cherif Ben Nasr
May 2012, Acta crystallographica. Section E, Structure reports online,
Copied contents to your clipboard!