Unusual coordination mode of tetradentate Schiff base cobalt(III) complexes. 2012

Anish Cyriac, and Jong Yeob Jeon, and Jobi Kodiyan Varghese, and Ji Hae Park, and Soo Young Choi, and Young Keun Chung, and Bun Yeoul Lee
Department of Molecular Science and Technology, Ajou University, Suwon, 443-749, Korea.

Contrary to the stereotype, Jacobsen's catalyst, chiral (salcy)Co(III)OAc adopts an unusual binding mode. The tetradentate {ONNO} ligand does not form a square plane but wraps cobalt in a cis-β fashion while acetate is chelating.

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