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Crystal growth, structure, and physical properties of LnCu2(Al,Si)5 (Ln = La and Ce). 2012
W Adam Phelan, and
Michael J Kangas, and
Brenton L Drake, and
Liang L Zhao, and
Jiakui K Wang, and
J F DiTusa, and
Emilia Morosan, and
Julia Y Chan
Department of Chemistry, Louisiana State University, Baton Rouge, Louisiana 70803, United States.
LnCu(2)(Al,Si)(5) (Ln = La and Ce) were synthesized and characterized. These compounds adopt the SrAu(2)Ga(5) structure type and crystallize in the tetragonal space group P4/mmm with unit cell dimensions of a ≈ 4.2 Å and c ≈ 7.9 Å. Herein, we report the structure as obtained from single crystal X-ray diffraction. Additionally, we report the magnetic susceptibility, magnetization, resistivity, and specific heat capacity data obtained for polycrystalline samples of LnCu(2)(Al,Si)(5) (Ln = La and Ce).
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