Sodium chloride template synthesis of cubic tin dioxide hollow particles for lithium ion battery applications. 2012

Rui Liu, and Shengchun Yang, and Fei Wang, and Xuegang Lu, and Zhimao Yang, and Bingjun Ding
School of Science, MOE Key Laboratory for Non-equilibrium Synthesis and Modulation of Condensed Matter, Shaan Xi, Xi'an Jiaotong University, 710049, People's Republic of China.

This paper describes a new synthesis and lithium ion charge-discharge property of tin dioxide (SnO(2)) hollow nanocubes. SnO(2) is one of the best-known anode materials for lithium-ion battery application because of its high lithiation-delithiation capacity. Hollow nanostructures with high surface area are preferred, because they accommodate large volume changes and maintain the structural stability of electrode materials during charge-discharge cycles. The SnO(2) hollow cubes made in this study had a discharge capacity of up to 1783 mA h g(-1) for the initial cycle and 546 mA h g(-1) after 30 cycles at a current density of 0.2 C between 0.02 and 2.0 V (vs Li/Li(+)).

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