Visible-light harvesting iridium complexes as singlet oxygen sensitizers for photooxidation of 1,5-dihydroxynaphthalene. 2012

Jifu Sun, and Jianzhang Zhao, and Huimin Guo, and Wanhua Wu
State Key Laboratory of Fine Chemicals, School of Chemical Engineering, E-208 West Campus, Dalian University of Technology, Dalian 116024, P. R. China.

Visible-light harvesting cyclometalated Ir(III) complexes were used as (1)O(2) sensitizers for the photooxidation of 1,5-dihydroxynaphthalene (DHN) and substantially improved photooxidation capability was observed compared to the conventional Ir(III) complex sensitizers that show no visible light-harvesting capabilities.

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