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Living radical polymerization of acrylates and acrylamides mediated by a versatile cobalt porphyrin complex. 2012
Beijing National Laboratory for Molecular Sciences, College of Chemistry and Molecular Engineering, Peking University, Beijing, 100871, China.
Living radical polymerization (LRP) of organic and water soluble acrylates and acrylamides was mediated by a versatile cobalt porphyrin complex (TMP-OH)Co. The capability of this cobalt complex to mediate LRP in both polar and non-polar media permits the direct synthesis of useful and previously difficult to prepare functional block copolymers.
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