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Hetaryl-substituted phosphonium-iodonium ylides in synthesis of heterocycles. 2012

Elena D Matveeva, and Tatyana A Podrugina, and Marina A Taranova, and Anastasiya M Ivanova, and Rolf Gleiter, and Nikolay S Zefirov
Department of Chemistry, Moscow State Lomonosov University, Russian Federation 119992, Moscow, Lenin Hills 1, Russia. matveeva@org.chem.msu.ru

A series of hitherto unknown hetaryl-substituted (in phosphonium part) phosphonium-iodonium ylides were synthesized. The reaction of these mixed phosphonium-iodonium ylides with acetylenes opens a way to new furyl annelated phosphinolines or unusually substituted phosphininofurans.

UI MeSH Term Description Entries
D009943 Organophosphorus Compounds Organic compounds that contain phosphorus as an integral part of the molecule. Included under this heading is broad array of synthetic compounds that are used as PESTICIDES and DRUGS. Organophosphorus Compound,Organopyrophosphorus Compound,Organopyrophosphorus Compounds,Compound, Organophosphorus,Compound, Organopyrophosphorus,Compounds, Organophosphorus,Compounds, Organopyrophosphorus
D005663 Furans Compounds with a 5-membered ring of four carbons and an oxygen. They are aromatic heterocycles. The reduced form is tetrahydrofuran. Tetrahydrofurans
D006571 Heterocyclic Compounds Cyclic compounds that include atoms other than carbon in their ring structure. Heterocyclic Compound,Compound, Heterocyclic,Compounds, Heterocyclic
D006847 Hydrocarbons, Iodinated Hydrocarbon compounds with one or more HYDROGEN atoms substituted with IODINE. Iodinated Hydrocarbons
D015394 Molecular Structure The location of the atoms, groups or ions relative to one another in a molecule, as well as the number, type and location of covalent bonds. Structure, Molecular,Molecular Structures,Structures, Molecular

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