Mechano-chemical oscillations and waves in reactive gels. 2012

Victor V Yashin, and Olga Kuksenok, and Pratyush Dayal, and Anna C Balazs
Chemical Engineering Department, University of Pittsburgh, Pittsburgh, PA 15261, USA.

We review advances in a new area of interdisciplinary research that concerns phenomena arising from inherent coupling between non-linear chemical dynamics and mechanics. This coupling provides a route for chemical-to-mechanical energy transduction, which enables materials to exhibit self-sustained oscillations and/or waves in both concentration and deformation fields. We focus on synthetic polymer gels, where the chemo-mechanical behavior can be engineered into the material. We provide a brief review of experimental observations on several types of chemo-mechanical oscillations in gels. Then, we discuss methods used to theoretically and computationally model self-oscillating polymer gels. The rest of the paper is devoted to describing results of theoretical and computational modeling of gels that undergo the oscillatory Belousov-Zhabotinsky (BZ) reaction. We discuss a remarkable form of mechano-chemical transduction in these materials, where the application of an applied force or mechanical contact can drive the system to switch between different dynamical behavior, or alter the mechanical properties of the material. Finally, we discuss ways in which photosensitive BZ gels could be used to fabricate biomimetic self-propelled objects. In particular, we describe how non-uniform illumination can be used to direct the movement of BZ gel 'worms' along complex paths, guiding them to bend, reorient and turn.

UI MeSH Term Description Entries
D008956 Models, Chemical Theoretical representations that simulate the behavior or activity of chemical processes or phenomena; includes the use of mathematical equations, computers, and other electronic equipment. Chemical Models,Chemical Model,Model, Chemical
D009991 Oscillometry The measurement of frequency or oscillation changes. Oscillometries
D005782 Gels Colloids with a solid continuous phase and liquid as the dispersed phase; gels may be unstable when, due to temperature or other cause, the solid phase liquefies; the resulting colloid is called a sol.
D014732 Vibration A continuing periodic change in displacement with respect to a fixed reference. (McGraw-Hill Dictionary of Scientific and Technical Terms, 6th ed) Vibrations

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