1-{(Z)-[3-(1-Hy-droxy-eth-yl)anilino]methyl-idene}naphthalen-2(1H)-one. 2013

Peter N Horton, and Mehmet Akkurt, and Shaaban K Mohamed, and Antar A Abdelhamid, and Adel A Marzouk
School of Chemistry, University of Southampton, Highfield, Southampton, SO17 1BJ England, England.

In the title compound, C19H17NO2, the dihedral angle between the benzene ring and the naphthalene ring system is 9.72 (5)°, while the torsion angle of the C-N-C-C bridging group is 179.24 (17)°. The methyl group of the 1-phenyl-ethanol moiety is disordered over two positions with a refined occupancy ratio of 0.775 (5):0.225 (5). The mol-ecular conformation is stabil-ized by an intra-molecular N-H⋯O hydrogen bond, which generates an S(6) ring motif. In the crystal, mol-ecules are linked by O-H⋯O hydrogen bonds, forming zigzag chains propagating along the c-axis direction. Neighbouring chains are linked via C-H⋯O inter-actions, forming a two-dimensional slab-like network parallel to the bc plane.

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