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Modification of molecular spin crossover in ultrathin films. 2013
Alex Pronschinske, and
Yifeng Chen, and
Geoffrey F Lewis, and
David A Shultz, and
Arrigo Calzolari, and
Marco Buongiorno Nardelli, and
Daniel B Dougherty
Department of Physics, North Carolina State University, Raleigh, North Carolina 27695, United States.
Scanning tunneling microscopy and local conductance mapping show spin-state coexistence in bilayer films of Fe[(H2Bpz2)2bpy] on Au(111) that is independent of temperature between 131 and 300 K. This modification of bulk behavior is attributed in part to the unique packing constraints of the bilayer film that promote deviations from bulk behavior. The local density of states measured for different spin states shows that high-spin molecules have a smaller transport gap than low-spin molecules and are in agreement with density functional theory calculations.
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