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Selective palladium-catalyzed hydroformylation of alkynes to α,β-unsaturated aldehydes. 2013

Xianjie Fang, and Min Zhang, and Ralf Jackstell, and Matthias Beller
Leibniz-Institut für Katalyse e. V. an der Universität Rostock, Albert-Einstein-Strasse 29a, 18059 Rostock, Germany.

Atom-efficient: A selective palladium catalyst system is used for the hydroformylation of alkynes (see picture). In this syngas reaction, various alkynes were smoothly transformed to synthetically interesting α,β-unsaturated aldehydes in good yields with high regio- and stereoselectivity.

UI MeSH Term Description Entries

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