Iodine-catalyzed regioselective sulfenylation of indoles with sulfonyl hydrazides.
2013
Fu-Lai Yang, and
Shi-Kai Tian
Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, China.
UI
MeSH Term
Description
Entries
D007211
Indoles
Benzopyrroles with the nitrogen at the number one carbon adjacent to the benzyl portion, in contrast to ISOINDOLES which have the nitrogen away from the six-membered ring.
D007455
Iodine
A nonmetallic element of the halogen group that is represented by the atomic symbol I, atomic number 53, and atomic weight of 126.90. It is a nutritionally essential element, especially important in thyroid hormone synthesis. In solution, it has anti-infective properties and is used topically.
Iodine-127,Iodine 127
D010084
Oxidation-Reduction
A chemical reaction in which an electron is transferred from one molecule to another. The electron-donating molecule is the reducing agent or reductant; the electron-accepting molecule is the oxidizing agent or oxidant. Reducing and oxidizing agents function as conjugate reductant-oxidant pairs or redox pairs (Lehninger, Principles of Biochemistry, 1982, p471).
Redox,Oxidation Reduction
D002384
Catalysis
The facilitation of a chemical reaction by material (catalyst) that is not consumed by the reaction.
Catalyses
D006834
Hydrazines
Substituted derivatives of hydrazine (formula H2N-NH2).
Hydrazide
D013237
Stereoisomerism
The phenomenon whereby compounds whose molecules have the same number and kind of atoms and the same atomic arrangement, but differ in their spatial relationships. (From McGraw-Hill Dictionary of Scientific and Technical Terms, 5th ed)
An element that is a member of the chalcogen family. It has an atomic symbol S, atomic number 16, and atomic weight [32.059; 32.076]. It is found in the amino acids cysteine and methionine.