4-(Dimethyl-amino)-pyridinium tetra-chloridoferrate(III). 2013

Amina Khadri, and Rafika Bouchene, and Sofiane Bouacida, and Hocine Merazig, and Thierry Roisnel
Laboratoire de Chimie Appliquée et Technologie des Matériaux LCATM, Université Oum El Bouaghi, Algeria ; Département Sciences de la Matière, Faculté des Sciences Exactes et Sciences de la Nature et de la Vie, Université Oum El Bouaghi, Algeria.

The title salt, (C7H11N2)[FeCl4], consists of one essentially planar (the r.m.s. deviation for all non-H atoms being 0.004 Å) 4-(dimethyl-amino)-pyridinium cation and a tetra-hedral tetra-chloridoferrate(III) anion. The cations and anions are arranged in layers parallel to (010). Besides electrostatic inter-actions, the crystal packing features N-H⋯Cl and C-H⋯Cl hydrogen bonds between cations and anions, forming a three-dimensional network.

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