5-Amino-6-methyl-quinolin-1-ium 3-carb-oxy-propano-ate. 2013

Kaliyaperumal Thanigaimani, and Nuridayanti Che Khalib, and Suhana Arshad, and Ibrahim Abdul Razak
School of Physics, Universiti Sains Malaysia, 11800 USM, Penang, Malaysia.

The asymmetric unit of the title salt, C10H11N2 (+)·C4H5O4 (-), consists of two independent 5-amino-6-methyl-quinolin-1-ium cations and two 3-carb-oxy-propano-ate anions. Both cations are protonated at the pyridine N atoms and are essentially planar, with maximum deviations of 0.026 (3) and 0.016 (2) Å. In the crystal, the cations and anions are linked via N-H⋯O and O-H⋯O hydrogen bonds, forming a layer parallel to the ab plane. In the layer, weak C-H⋯O hydrogen bonds and π-π stacking inter-actions, with centroid-to-centroid distances of 3.7283 (15) and 3.8467 (15) Å, are observed. The crystal structure also features weak C-H⋯O hydrogen bonds between the layers.

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