Anomalous intrinsic viscosity of octadecylamine-functionalised carbon nanotubes in suspension. 2013

K J Donovan, and K Scott
School of Physics and Astrophysics, Queen Mary, University of London, Mile End Road, London E1 4NS, United Kingdom. k.j.donovan@qmul.ac.uk

Single walled carbon nanotubes, SWCNTs, are used as a model cylinder of nanoscopic dimensions for testing rheological theories of how addition of cylindrical particles affects the viscosity of a suspension of such particles. Using the rate of growth of the accompanying induced linear dichroism following application of an applied electric field, the dynamics of carbon nanotube alignment is studied in suspensions of octadecylamine functionalised single walled carbon nanotubes, ODA-SWCNTs, in 1,2 dichloroethane. From such measurements the viscosity of the suspension is measured as the concentration of the suspension is varied. While working within the dilute limit the viscosity is found to increase linearly with concentration and the intrinsic viscosity of the suspension is found to be 8000. This anomalously high intrinsic viscosity is compared with the predictions of various models for a rigid cylinder and found to be incompatible with any of the current models. Some suggestions are made as to the way this ODA-SWCNT result may be eventually accommodated within other models.

UI MeSH Term Description Entries
D000588 Amines A group of compounds derived from ammonia by substituting organic radicals for the hydrogens. (From Grant & Hackh's Chemical Dictionary, 5th ed) Amine
D013535 Suspensions Colloids with liquid continuous phase and solid dispersed phase; the term is used loosely also for solid-in-gas (AEROSOLS) and other colloidal systems; water-insoluble drugs may be given as suspensions. Suspension
D014783 Viscosity The resistance that a gaseous or liquid system offers to flow when it is subjected to shear stress. (From McGraw-Hill Dictionary of Scientific and Technical Terms, 6th ed) Viscosities
D015394 Molecular Structure The location of the atoms, groups or ions relative to one another in a molecule, as well as the number, type and location of covalent bonds. Structure, Molecular,Molecular Structures,Structures, Molecular
D037742 Nanotubes, Carbon Nanometer-sized tubes composed mainly of CARBON. Such nanotubes are used as probes for high-resolution structural and chemical imaging of biomolecules with ATOMIC FORCE MICROSCOPY. Buckytubes,Carbon Nanotubes,Nanoribbons,Buckytube,Carbon Nanotube,Nanoribbon,Nanotube, Carbon

Related Publications

K J Donovan, and K Scott
February 2005, Chemical communications (Cambridge, England),
K J Donovan, and K Scott
November 2013, Physical review. E, Statistical, nonlinear, and soft matter physics,
K J Donovan, and K Scott
February 2011, Chemical communications (Cambridge, England),
K J Donovan, and K Scott
January 2005, Physical review letters,
K J Donovan, and K Scott
August 2019, IET nanobiotechnology,
K J Donovan, and K Scott
March 2019, Journal of colloid and interface science,
K J Donovan, and K Scott
October 2017, ACS nano,
K J Donovan, and K Scott
October 2008, Chemical communications (Cambridge, England),
Copied contents to your clipboard!