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Reversible carbon-carbon bond formation between carbonyl compounds and a ruthenium pincer complex. 2013

Chelsea A Huff, and Jeff W Kampf, and Melanie S Sanford
Department of Chemistry, University of Michigan, 930 North University Avenue, Ann Arbor, Michigan 48109, USA.

This communication describes the reversible reaction of a ruthenium pincer complex with a variety of carbonyl compounds. Both NMR spectroscopic and X-ray crystallographic characterization of isomeric carbonyl adducts are reported, and the equilibrium constants for carbonyl binding have been determined.

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