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Hydrogenation of nitroarenes using defined iron-phosphine catalysts. 2013
Gerrit Wienhöfer, and
Mario Baseda-Krüger, and
Carolin Ziebart, and
Felix A Westerhaus, and
Wolfgang Baumann, and
Ralf Jackstell, and
Kathrin Junge, and
Matthias Beller
Leibniz-Institut für Katalyse e.V., Albert Einstein Straße. 29a, 18059 Rostock, Germany. matthias.beller@catalysis.de.
A novel iron-catalyzed hydrogenation of nitroarenes to the corresponding amines is reported. An in situ combination of Fe(BF4)2·6H2O and phosphine allows for highly selective hydrogenation of a broad range of aromatic and nitroarenes tolerating different functional groups.
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