Catalytic pyrolysis of sugarcane bagasse by using microwave heating. 2013

Wen-Hui Kuan, and Yu-Fong Huang, and Chi-Cheng Chang, and Shang-Lien Lo
Department of Safety, Health and Environmental Engineering, Ming Chi University of Technology, 84, Gong-Juan Rd., Taishan, New Taipei 243, Taiwan.

The aim of this study was to research the catalytic effects on the microwave pyrolysis of sugarcane bagasse and thus to discuss the reaction performance, product distribution, and kinetic analysis. With the addition of metal-oxides served as catalysts, reaction results such as mass reduction ratio and reaction rate increased, even the maximum temperature decreased. Adding either NiO or CaO slightly increased the production of H2, while adding either CuO or MgO slightly decreased it. The addition of either CaO or MgO enhanced the gaseous production, and either NiO or CuO addition enhanced the liquid production. There could be several secondary reactions such as self-gasification and interactions among the gases originally produced during the pyrolysis stage to alter the composition of gaseous product and the final three-phase product distribution. The catalyst addition slightly increased the activation energy but greatly increased the pre-exponential factor.

UI MeSH Term Description Entries
D007700 Kinetics The rate dynamics in chemical or physical systems.
D008670 Metals Electropositive chemical elements characterized by ductility, malleability, luster, and conductance of heat and electricity. They can replace the hydrogen of an acid and form bases with hydroxyl radicals. (Grant & Hackh's Chemical Dictionary, 5th ed) Metal
D008872 Microwaves That portion of the electromagnetic spectrum from the UHF (ultrahigh frequency) radio waves and extending into the INFRARED RAYS frequencies. EHF Waves,Extremely High Frequency Radio Waves,Micro Wave,Micro Waves,Ultrahigh Frequency Waves,Microwave Radiation,EHF Wave,Micro Waves,Microwave,Microwave Radiations,Radiation, Microwave,Ultrahigh Frequency Wave,Wave, EHF,Wave, Micro,Wave, Ultrahigh Frequency,Waves, Micro
D010087 Oxides Binary compounds of oxygen containing the anion O(2-). The anion combines with metals to form alkaline oxides and non-metals to form acidic oxides. Oxide
D012037 Refuse Disposal The discarding or destroying of garbage, sewage, or other waste matter or its transformation into something useful or innocuous. Waste Disposal, Solid,Disposal, Refuse,Disposal, Solid Waste,Disposals, Refuse,Disposals, Solid Waste,Refuse Disposals,Solid Waste Disposal,Solid Waste Disposals,Waste Disposals, Solid
D002384 Catalysis The facilitation of a chemical reaction by material (catalyst) that is not consumed by the reaction. Catalyses
D002482 Cellulose A polysaccharide with glucose units linked as in CELLOBIOSE. It is the chief constituent of plant fibers, cotton being the purest natural form of the substance. As a raw material, it forms the basis for many derivatives used in chromatography, ion exchange materials, explosives manufacturing, and pharmaceutical preparations. Alphacel,Avicel,Heweten,Polyanhydroglucuronic Acid,Rayophane,Sulfite Cellulose,alpha-Cellulose,Acid, Polyanhydroglucuronic,alpha Cellulose
D005740 Gases The vapor state of matter; nonelastic fluids in which the molecules are in free movement and their mean positions far apart. Gases tend to expand indefinitely, to diffuse and mix readily with other gases, to have definite relations of volume, temperature, and pressure, and to condense or liquefy at low temperatures or under sufficient pressure. (Grant & Hackh's Chemical Dictionary, 5th ed)
D006358 Hot Temperature Presence of warmth or heat or a temperature notably higher than an accustomed norm. Heat,Hot Temperatures,Temperature, Hot,Temperatures, Hot
D006361 Heating The application of heat to raise the temperature of the environment, ambient or local, or the systems for accomplishing this effect. It is distinguished from HEAT, the physical property and principle of physics.

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