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Mechanistic insights and kinetic analysis for the oxidative hydroxylation of arylboronic acids by visible light photoredox catalysis: a metal-free alternative. 2013

Spencer P Pitre, and Christopher D McTiernan, and Hossein Ismaili, and Juan C Scaiano
Department of Chemistry and Centre for Catalysis Research and Innovation, University of Ottawa , 10 Marie Curie, Ottawa K1N 6N5, Canada.

The photocatalytic hydroxylation of boronic acids with methylene blue as photosensitizer proceeds with high efficiency. Detailed time-resolved studies of the relevant rate constants provide a clear mechanistic understanding of excited-state processes and guided the selection of the photocatalyst and the optimization of experimental conditions.

UI MeSH Term Description Entries

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