A two-dimensional zeolitic imidazolate framework with a cushion-shaped cavity for CO2 adsorption. 2013

Rizhi Chen, and Jianfeng Yao, and Qinfen Gu, and Stef Smeets, and Christian Baerlocher, and Haoxue Gu, and Dunru Zhu, and William Morris, and Omar M Yaghi, and Huanting Wang
Department of Chemical Engineering, Monash University, Clayton, Victoria 3800, Australia. huanting.wang@monash.edu.

A new two-dimensional zeolitic imidazolate framework (named as ZIF-L) was synthesized in zinc salt and 2-methylimidazole (Hmim) aqueous solution at room temperature. ZIF-L (Zn(mim)2·(Hmim)1/2·(H2O)3/2 or C10H16N5O3/2Zn) has unique cushion-shaped cavities and leaf-like crystal morphology, and exhibits excellent CO2 adsorption properties.

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