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Methyl N-(di-meth-oxy-phosphor-yl)carbamate. 2013

Vladimir Ovchynnikov
Department of Inorganic Chemistry, Kiev National Taras Shevchenko University, Vladimirskaya St. 64/13, Kiev 01601, Ukraine.

In the title compound, CH3OC(O)NHP(O)(OCH3)2, the P atom has a slightly distorted tetra-hedral configuration. The mixed imide moiety can be described as cisoid-transoid in which the two opposing dipoles (P=O and C=O) are oriented with a O=C⋯P=O torsion angle of 150.88(18)°. In the crystal, molecules are linked by pairs of N-H⋯O hydrogen bonds, forming inversion dimers.

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