Copper-catalyzed three-component oxytrifluoromethylation of alkenes with sodium trifluoromethanesulfinate and hydroxamic acid.
2013
Xin-Yi Jiang, and
Feng-Ling Qing
Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032 (China).
UI
MeSH Term
Description
Entries
D010084
Oxidation-Reduction
A chemical reaction in which an electron is transferred from one molecule to another. The electron-donating molecule is the reducing agent or reductant; the electron-accepting molecule is the oxidizing agent or oxidant. Reducing and oxidizing agents function as conjugate reductant-oxidant pairs or redox pairs (Lehninger, Principles of Biochemistry, 1982, p471).
Redox,Oxidation Reduction
D002384
Catalysis
The facilitation of a chemical reaction by material (catalyst) that is not consumed by the reaction.
Catalyses
D003300
Copper
A heavy metal trace element with the atomic symbol Cu, atomic number 29, and atomic weight 63.55.
Copper-63,Copper 63
D006877
Hydroxamic Acids
A class of weak acids with the general formula R-CONHOH.
Unsaturated hydrocarbons of the type Cn-H2n, indicated by the suffix -ene. (Grant & Hackh's Chemical Dictionary, 5th ed, p408)
Alkene,Olefin,Olefins,Pentene,Pentenes
D013237
Stereoisomerism
The phenomenon whereby compounds whose molecules have the same number and kind of atoms and the same atomic arrangement, but differ in their spatial relationships. (From McGraw-Hill Dictionary of Scientific and Technical Terms, 5th ed)