Biomaterial Database

Residues and enantiomeric profiling of organochlorine pesticides in sediments from Xinghua Bay, southern East China Sea. 2014

Bin Xue, and Qiao Z Tang, and Mei Q Jin, and Shan S Zhou, and Hai S Zhang

a The Faculty of Earth Resources , China University of Geosciences , Wuhan , China.

The spatial distribution and chiral signatures of organochlorine pesticides (OCPs) in the surface sediments of Xinghua Bay, southern East China Sea, were investigated. The total OCP concentrations ranged from 9.15 to 40.5 ng/g dry weight, with a predominance of hexachlorocyclohexanes (HCHs) and dichlorodiphenyltrichloroethanes (DDTs). The isomer ratios of α-HCH/γ-HCH (less than 1.0) and the predominant β-HCH implied that HCH residues were derived not only from historical technical HCH use but also from the additional use of lindane in this area. The isomer ratios of p,p'-DDT/(p,p'-DDD + p,p'-DDE) and o,p'-DDT/p,p''-DDT, and a strong correlation (R = 0.83, P < 0.001) between p,p'-DDE and o,p'-DDT depicted a cocktail input pattern of dicofol-type DDT and technical DDT. Moreover, the fact that only cis-chlordane was detectable for all sampling stations suggested the past application of technical chlordane. Based on the sediment quality guidelines (SQG), γ-HCH is the main OCP species of ecotoxicological concern in Xinghua Bay. Enantiomeric analysis showed that the (+)-enantiomers of α-HCH and o,p'-DDT were more prevalent than the (-)-enantiomers in most samples, whereas both racemic and nonracemic residues existed for o,p'-DDD. These results implied that the SQG of chiral OCPs should be reassessed using concentrations of their individual enantiomers.

UI	MeSH Term	Description	Entries
D007306	Insecticides	Pesticides designed to control insects that are harmful to man. The insects may be directly harmful, as those acting as disease vectors, or indirectly harmful, as destroyers of crops, food products, or textile fabrics.	Insecticide
D010573	Pesticide Residues	Pesticides or their breakdown products remaining in the environment following their normal use or accidental contamination.	Pesticide Residue,Residue, Pesticide,Residues, Pesticide
D002681	China	A country spanning from central Asia to the Pacific Ocean.	Inner Mongolia,Manchuria,People's Republic of China,Sinkiang,Mainland China
D002849	Chromatography, Gas	Fractionation of a vaporized sample as a consequence of partition between a mobile gaseous phase and a stationary phase held in a column. Two types are gas-solid chromatography, where the fixed phase is a solid, and gas-liquid, in which the stationary phase is a nonvolatile liquid supported on an inert solid matrix.	Chromatography, Gas-Liquid,Gas Chromatography,Chromatographies, Gas,Chromatographies, Gas-Liquid,Chromatography, Gas Liquid,Gas Chromatographies,Gas-Liquid Chromatographies,Gas-Liquid Chromatography
D004784	Environmental Monitoring	The monitoring of the level of toxins, chemical pollutants, microbial contaminants, or other harmful substances in the environment (soil, air, and water), workplace, or in the bodies of people and animals present in that environment.	Monitoring, Environmental,Environmental Surveillance,Surveillance, Environmental
D006843	Hydrocarbons, Chlorinated	Hydrocarbon compounds with one or more of the hydrogens replaced by CHLORINE.	Chlorinated Hydrocarbon,Chlorinated Hydrocarbons,Organochlorine Compound,Chlorine Compounds, Organic,Organochlorine Compounds,Compound, Organochlorine,Compounds, Organic Chlorine,Compounds, Organochlorine,Hydrocarbon, Chlorinated,Organic Chlorine Compounds
D014874	Water Pollutants, Chemical	Chemical compounds which pollute the water of rivers, streams, lakes, the sea, reservoirs, or other bodies of water.	Chemical Water Pollutants,Landfill Leachate,Leachate, Landfill,Pollutants, Chemical Water
D061006	Bays	An area of water mostly surrounded by land, usually smaller than a gulf, and affording access to the sea.	Inlets,Bay,Inlet
D019015	Geologic Sediments	A mass of organic or inorganic solid fragmented material, or the solid fragment itself, that comes from the weathering of rock and is carried by, suspended in, or dropped by air, water, or ice. It refers also to a mass that is accumulated by any other natural agent and that forms in layers on the earth's surface, such as sand, gravel, silt, mud, fill, or loess. (McGraw-Hill Dictionary of Scientific and Technical Terms, 4th ed, p1689)	Marine Oil Snow,Sediments, Geologic,Sediments, Marine,Geologic Sediment,Marine Snow,Sediment, Geologic,Marine Oil Snows,Marine Sediment,Marine Sediments,Oil Snow, Marine,Sediment, Marine,Snow, Marine Oil