-transparent.png){kind=logo}
Palladium-catalyzed direct thiolation of aryl C-H bonds with disulfides. 2014
Masayuki Iwasaki, and
Miki Iyanaga, and
Yuta Tsuchiya, and
Yugo Nishimura, and
Wenjuan Li, and
Zhiping Li, and
Yasushi Nishihara
Division of Earth, Life, and Molecular Sciences, Graduate School of Natural Science and Technology, Okayama University, 3-1-1 Tsushimanaka, Kita-ku, Okayama 700-8530 (Japan), Fax: (+81) 86-251-7855.
A catalytic variant of the direct thiolation of arenes, bearing directing groups, with disulfides or thiols has been developed under palladium and copper co-catalysis. Both sulfenyl moieties of the disulfide could be incorporated into the thiolated products, therefore, the reactions reached completion with only half an equivalent of disulfide, with respect to the starting arene. Experimental evidence suggested that the reaction proceeds through a Pd(II)/Pd(IV) mechanism.
| UI | MeSH Term | Description | Entries |
|---|
Related Publications
Masayuki Iwasaki, and
Miki Iyanaga, and
Yuta Tsuchiya, and
Yugo Nishimura, and
Wenjuan Li, and
Zhiping Li, and
Yasushi Nishihara
July 2019,
Organic & biomolecular chemistry,
Masayuki Iwasaki, and
Miki Iyanaga, and
Yuta Tsuchiya, and
Yugo Nishimura, and
Wenjuan Li, and
Zhiping Li, and
Yasushi Nishihara
April 2015,
Chemical communications (Cambridge, England),
Masayuki Iwasaki, and
Miki Iyanaga, and
Yuta Tsuchiya, and
Yugo Nishimura, and
Wenjuan Li, and
Zhiping Li, and
Yasushi Nishihara
April 2014,
Organic letters,
Masayuki Iwasaki, and
Miki Iyanaga, and
Yuta Tsuchiya, and
Yugo Nishimura, and
Wenjuan Li, and
Zhiping Li, and
Yasushi Nishihara
October 2016,
Dalton transactions (Cambridge, England : 2003),
Masayuki Iwasaki, and
Miki Iyanaga, and
Yuta Tsuchiya, and
Yugo Nishimura, and
Wenjuan Li, and
Zhiping Li, and
Yasushi Nishihara
September 2014,
Organic letters,
Masayuki Iwasaki, and
Miki Iyanaga, and
Yuta Tsuchiya, and
Yugo Nishimura, and
Wenjuan Li, and
Zhiping Li, and
Yasushi Nishihara
March 2015,
Chemical communications (Cambridge, England),
Masayuki Iwasaki, and
Miki Iyanaga, and
Yuta Tsuchiya, and
Yugo Nishimura, and
Wenjuan Li, and
Zhiping Li, and
Yasushi Nishihara
August 2009,
Organic letters,
Masayuki Iwasaki, and
Miki Iyanaga, and
Yuta Tsuchiya, and
Yugo Nishimura, and
Wenjuan Li, and
Zhiping Li, and
Yasushi Nishihara
August 2009,
Organic letters,
Masayuki Iwasaki, and
Miki Iyanaga, and
Yuta Tsuchiya, and
Yugo Nishimura, and
Wenjuan Li, and
Zhiping Li, and
Yasushi Nishihara
April 2015,
Organic letters,
Masayuki Iwasaki, and
Miki Iyanaga, and
Yuta Tsuchiya, and
Yugo Nishimura, and
Wenjuan Li, and
Zhiping Li, and
Yasushi Nishihara
July 2013,
Journal of the American Chemical Society,
