Bromate removal from aqueous solutions by ordered mesoporous carbon. 2014

Chunhua Xu, and Xiaohong Wang, and Xiaolei Shi, and Sheng Lin, and Liujia Zhu, and Yaming Che

We investigated the feasibility of using ordered mesoporous carbon (OMC) for bromate removal from water. Batch experiments were performed to study the influence of various experimental parameters such as the effect of contact time, adsorbent dosage, initial bromate concentration, temperature, pH and effect of competing anions on bromate removal by OMC. The adsorption kinetics indicates that the uptake rate ofbromate was rapid at the beginning: 85% adsorption was completed in 1 h and equilibrium was achieved within 3 h. The sorption process was well described with pseudo-second-order kinetics. The maximum adsorption capacity of OMC for bromate removal was 17.6 mg g(-1) at 298 K. The adsorption data fit the Freundlich model well. The amount of bromate removed was found to be proportional to the influent bromate concentration. The effects of competing anions and solution pH (3-11) were negligible. These limited data suggest that OMC can be effectively utilized for bromate removal from drinking water.

UI MeSH Term Description Entries
D007700 Kinetics The rate dynamics in chemical or physical systems.
D001959 Bromates Negative ions or salts derived from bromic acid, HBrO3. Bromate
D002244 Carbon A nonmetallic element with atomic symbol C, atomic number 6, and atomic weight [12.0096; 12.0116]. It may occur as several different allotropes including DIAMOND; CHARCOAL; and GRAPHITE; and as SOOT from incompletely burned fuel. Carbon-12,Vitreous Carbon,Carbon 12,Carbon, Vitreous
D006863 Hydrogen-Ion Concentration The normality of a solution with respect to HYDROGEN ions; H+. It is related to acidity measurements in most cases by pH pH,Concentration, Hydrogen-Ion,Concentrations, Hydrogen-Ion,Hydrogen Ion Concentration,Hydrogen-Ion Concentrations
D000327 Adsorption The adhesion of gases, liquids, or dissolved solids onto a surface. It includes adsorptive phenomena of bacteria and viruses onto surfaces as well. ABSORPTION into the substance may follow but not necessarily. Adsorptions
D000838 Anions Negatively charged atoms, radicals or groups of atoms which travel to the anode or positive pole during electrolysis. Anion
D012996 Solutions The homogeneous mixtures formed by the mixing of a solid, liquid, or gaseous substance (solute) with a liquid (the solvent), from which the dissolved substances can be recovered by physical processes. (From Grant & Hackh's Chemical Dictionary, 5th ed) Solution
D013696 Temperature The property of objects that determines the direction of heat flow when they are placed in direct thermal contact. The temperature is the energy of microscopic motions (vibrational and translational) of the particles of atoms. Temperatures
D013816 Thermodynamics A rigorously mathematical analysis of energy relationships (heat, work, temperature, and equilibrium). It describes systems whose states are determined by thermal parameters, such as temperature, in addition to mechanical and electromagnetic parameters. (From Hawley's Condensed Chemical Dictionary, 12th ed) Thermodynamic
D014867 Water A clear, odorless, tasteless liquid that is essential for most animal and plant life and is an excellent solvent for many substances. The chemical formula is hydrogen oxide (H2O). (McGraw-Hill Dictionary of Scientific and Technical Terms, 4th ed) Hydrogen Oxide

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