3-(2,3-Dioxoindolin-1-yl)propane-nitrile. 2014

Fatima-Zahrae Qachchachi, and Youssef Kandri Rodi, and El Mokhtar Essassi, and Michael Bodensteiner, and Lahcen El Ammari
Laboratoire de Chimie Organique Appliquée, Université Sidi Mohamed Ben Abdallah, Faculté des Sciences et Techniques, Route d'Immouzzer, BP 2202 Fès, Morocco.

The asymmetric unit of the title compound, C11H8N2O2, contains two independent mol-ecules (A and B). Each mol-ecule is build up from fused five- and six-membered rings with the former linked to a cyano-ethyl group. The indoline ring and two carbonyl O atoms of each mol-ecule are nearly coplanar, with the largest deviations from the mean planes being 0.0198 (9) (mol-ecule A) and 0.0902 (9) Å (mol-ecule B), each by a carbonyl O atom. The fused ring system is nearly perpendicular to the mean plane passing through the cyano-ethyl chains, as indicated by the dihedral angles between them of 69.72 (9) (mol-ecule A) and 69.15 (9)° (mol-ecule B). In the crystal, mol-ecules are linked by C-H⋯O and π-π [inter-centroid distance between inversion-related indoline (A) rings = 3.6804 (7) Å] inter-actions into a double layer that stacks along the a-axis direction.

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