Enhanced microwave absorption property of reduced graphene oxide (RGO)-MnFe2O4 nanocomposites and polyvinylidene fluoride. 2014

Xiao-Juan Zhang, and Guang-Sheng Wang, and Wen-Qiang Cao, and Yun-Zhao Wei, and Jun-Fei Liang, and Lin Guo, and Mao-Sheng Cao
Key Laboratory of Bio-Inspired Smart Interfacial Science and Technology of Ministry of Education, School of Chemistry and Environment, Beihang University , Beijing 100191, People's Republic of China.

MnFe2O4 nanoparticles have been synthesized on a large scale by a simple hydrothermal process in a wild condition, and the RGO/MnFe2O4 nanocomposites were also prepared under ultrasonic treatment based on the synthesized nanoparticles. The absorption properties of MnFe2O4/wax, RGO/MnFe2O4/wax and the RGO/MnFe2O4/PVDF (polyvinylidene fluoride) composites were studied; the results indicated that the RGO/MnFe2O4/PVDF composites show the most excellent wave absorption properties. The minimum reflection loss of RGO/MnFe2O4/PVDF composites with filler content of 5 wt % can reach -29.0 dB at 9.2 GHz, and the bandwidth of frequency less than -10 dB is from 8.00 to 12.88 GHz. The wave absorbing mechanism can be attributed to the dielectric loss, magnetic loss and the synergetic effect between RGO+MnFe2O4, RGO+PVDF and MnFe2O4+PVDF.

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