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Bis(tetra-phenyl-phospho-nium) tetra-chlorido-cobaltate(II). 2014
Zeghouan Ouahida, and
Nasreddine Hadjadj, and
Fatiha Guenifa, and
Lamia Bendjeddou, and
Hocine Merazig
Unité de Recherche Chimie de l'Environnement et Moléculaire Structurale (CHEMS), Faculté des Sciences Exactes, Campus Chaabet Ersas, Université Constantine I, 25000 Constantine, Algeria.
The title compound, (C24H20P)2[CoCl4], was prepared under hydro-thermal conditions. In the crystal, the tetra-phenyl-phospho-nium cations are linked by pairs of weak C-H⋯π inter-actions into supra-molecular dimers; the Co(II) cations lie on twofold rotation axes and the tetra-hedral [CoCl4](2-) anions are linked with the tetra-phenyl-phospho-nium cations via weak C-H⋯Cl hydrogen bonds.
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