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Controlled self-assembly of helical nano-ribbons formed by achiral amphiphiles. 2015
Bo Song, and
Bin Liu, and
Yingzhi Jin, and
Xingxing He, and
Danting Tang, and
Guanglu Wu, and
Shouchun Yin
Suzhou Key Laboratory of Macromolecular Design and Precision Synthesis, Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, P. R. China.
Helical nano-ribbons with a large aspect ratio were obtained through the self-assembly of an achiral amphiphile. The symmetry breaking is attributed to the orderly but twisted stacking of terpyridine groups. In addition, the morphology of the assemblies can be tuned by the coordination between terpyridine and Zn(2+) ion.
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