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Stereoselective cathodic synthesis of 8-substituted (1R,3R,4S)-menthylamines. 2015

Carolin Edinger, and Jörn Kulisch, and Siegfried R Waldvogel
Institut für Organische Chemie, Johannes Gutenberg-Universität Mainz, Duesbergweg 10-14, 55128 Mainz, Germany.

The electrochemical generation of menthylamines from the corresponding menthone oximes equipped with an additional substituent in position 8 is described. Due to 1,3-diaxial interactions a pronounced diastereoselectivity for the menthylamines is found.

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