Ultrasound assisted synthesis of methyl butyrate using heterogeneous catalyst. 2015

P N Dange, and A V Kulkarni, and V K Rathod
Department of Chemical Engineering, Institute of Chemical Technology, Matunga (E), Mumbai 400019, India.

Ultrasound assisted esterification of butyric acid with methanol was investigated in an ultrasound irradiated isothermal batch reactor using acid ion-exchange resin (amberlyst-15) as a catalyst. Effect of parameters such as temperature (323-353 K), catalyst loading (0-8.5%w/w), alcohol to acid ratio, M (2-6), ultrasound power (0-145 W), duty cycle (0-85%) and amount of molecular sieves added (0-11%w/w) on the rate of reaction was studied. At optimized parameters, a maximum conversion of 91.64% was obtained in 120 min in presence of ultrasound. Experimental kinetic data were correlated by using Eley-Rideal (ER) and Langmuir-Hinshelwood-Hougen-Watson (LHH W) models taking into account reverse reaction. Studies showed that single site LHHW with reactants and products both adsorbing on catalyst surface was most suited for the obtained experimental data. Activation energy determined based on heterogeneous kinetics was in the range 49.31-57.54 kJ/mol while it was 18.29 kJ/mol using homogeneous model.

UI MeSH Term Description Entries

Related Publications

P N Dange, and A V Kulkarni, and V K Rathod
January 2015, Ultrasonics sonochemistry,
P N Dange, and A V Kulkarni, and V K Rathod
April 2019, Ultrasonics sonochemistry,
P N Dange, and A V Kulkarni, and V K Rathod
January 2018, Ultrasonics sonochemistry,
P N Dange, and A V Kulkarni, and V K Rathod
September 2012, Ultrasonics sonochemistry,
P N Dange, and A V Kulkarni, and V K Rathod
January 2016, Journal of hazardous materials,
P N Dange, and A V Kulkarni, and V K Rathod
March 2017, Ultrasonics sonochemistry,
P N Dange, and A V Kulkarni, and V K Rathod
June 2008, Chemistry, an Asian journal,
P N Dange, and A V Kulkarni, and V K Rathod
January 2014, Ultrasonics sonochemistry,
Copied contents to your clipboard!