Preparation of CNC-dispersed Fe3O4 nanoparticles and their application in conductive paper. 2015

Kai Liu, and Joseph Nasrallah, and Lihui Chen, and Liulian Huang, and Yonghao Ni
College of Material Engineering, Fujian Agriculture and Forestry University, Fuzhou 350002, China; Limerick Pulp and Paper Centre, Department of Chemical Engineering, University of New Brunswick, Fredericton, NB, Canada E3B 5A3. Electronic address: liuk1103@163.com.

Well-dispersed Fe3O4 nanoparticles (NPs) were synthesized by a co-precipitation method in the presence of cellulose nano-crystals (CNC) as the template. The thus prepared Fe3O4 NPs were then used as a coating agent for the preparation of conductive paper. Fourier transform infrared spectroscopy (FTIR) results revealed that the Fe3O4 NPs were immobilized on the CNC through interactions between the hydroxyl groups of CNC and Fe3O4. Scanning transmission electron microscopy (STEM) images showed that the Fe3O4 NPs prepared in the presence of CNC can be dispersed in the CNC network, while the Fe3O4 NPs prepared in the absence of CNC tended to aggregate in aqueous solutions. The conductivity of the Fe3O4 NPs coated paper can reach to 0.0269 S/m at the coating amount of 14.75 g/m(2) Fe3O4/CNC nanocomposites. Therefore, the thus obtained coated paper can be potentially used as anti-static packaging material in the packaging field.

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