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High-Performance Polyoxometalate-Based Cathode Materials for Rechargeable Lithium-Ion Batteries. 2015

Jia-Jia Chen, and Mark D Symes, and Shao-Cong Fan, and Ming-Sen Zheng, and Haralampos N Miras, and Quan-Feng Dong, and Leroy Cronin
State Key Laboratory of Physical Chemistry of Solid Surfaces, Collaborative Innovation Centre of Chemistry for Energy Materials, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, Fujian, 361005, China.

The polyoxovanadate cluster Li7[V15O36(CO3)] is shown to be an active cathode material in Li-ion batteries, delivering a capacity of 250 mA h g(-1) at 50 mA g(-1) and 140 mA h g(-1) at 10 A g(-1). Li-ion diffusion is rapid in this material and gives rise to an impressive maximum power density output of 25.7 kW kg(-1) (55 kW L(-1)).

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