Biomaterial Database

Effects of processing on the properties of chitosan/cellulose nanocrystal films. 2015

Hande Celebi, and Ayse Kurt

Faculty of Engineering, Department of Chemical Engineering, Anadolu University, Eskisehir 26555, Turkey. Electronic address: handed@anadolu.edu.tr.

Biocomposites of chitosan (CS)/cellulose nanocrystals (CN) were prepared by using solution casting method. Influences of solution preparation method and CN content on the properties of composites were investigated. Mechanical stirring/ultrasonication or microfluidization were used to disperse nanocrystals in the chitosan matrix. The prepared nanocomposites were characterized by FTIR, XRD, SEM, DSC, TGA, TMA and contact angle measurements. SEM analysis revealed that microfluidization decreased CN aggregates in matrix. Formation of hydrogen bonds between CS and CN in nanocomposites prepared by using microfluidization was confirmed by FTIR spectroscopy. This high interaction led to an increment of the crystallinity of chitosan films. Tg values within a range of 53-58°C were obtained in DSC and TMA measurements. The thermal stability of CS film showed no significant effect of CN addition, whereas contact angle measurements revealed that CN addition resulted in an increment of hydrophilicity of chitosan films.

UI	MeSH Term	Description	Entries
D002482	Cellulose	A polysaccharide with glucose units linked as in CELLOBIOSE. It is the chief constituent of plant fibers, cotton being the purest natural form of the substance. As a raw material, it forms the basis for many derivatives used in chromatography, ion exchange materials, explosives manufacturing, and pharmaceutical preparations.	Alphacel,Avicel,Heweten,Polyanhydroglucuronic Acid,Rayophane,Sulfite Cellulose,alpha-Cellulose,Acid, Polyanhydroglucuronic,alpha Cellulose
D013010	Sonication	The application of high intensity ultrasound to liquids.	Sonications
D013696	Temperature	The property of objects that determines the direction of heat flow when they are placed in direct thermal contact. The temperature is the energy of microscopic motions (vibrational and translational) of the particles of atoms.	Temperatures
D048271	Chitosan	Deacetylated CHITIN, a linear polysaccharide of deacetylated beta-1,4-D-glucosamine. It is used in HYDROGEL and to treat WOUNDS.	Poliglusam
D053758	Nanoparticles	Nanometer-sized particles that are nanoscale in three dimensions. They include nanocrystaline materials; NANOCAPSULES; METAL NANOPARTICLES; DENDRIMERS, and QUANTUM DOTS. The uses of nanoparticles include DRUG DELIVERY SYSTEMS and cancer targeting and imaging.	Nanocrystalline Materials,Nanocrystals,Material, Nanocrystalline,Materials, Nanocrystalline,Nanocrystal,Nanocrystalline Material,Nanoparticle
D053761	Nanocomposites	Nanometer-scale composite structures composed of organic molecules intimately incorporated with inorganic molecules. (Glossary of Biotechnology and Nanobiotechology Terms, 4th ed)	Nanocomposite
D055595	Mechanical Phenomena	The properties and processes of materials that affect their behavior under force.	Mechanical Concepts,Mechanical Processes,Mechanical Phenomenon,Mechanical Process,Concept, Mechanical,Concepts, Mechanical,Mechanical Concept,Phenomena, Mechanical,Phenomenon, Mechanical,Process, Mechanical,Processes, Mechanical