Enhanced Ionic Conductivity and Power Generation Using Ion-Exchange Resin Beads in a Reverse-Electrodialysis Stack. 2015

Bopeng Zhang, and Haiping Gao, and Yongsheng Chen
School of Civil and Environmental Engineering, Georgia Institute of Technology , Atlanta, Georgia 30332, United States.

Reverse electrodialysis (RED) is a promising technique for harvesting energy by mixing seawater with river water. The energy production is usually limited by ionic conductivity in dilute compartments of a RED system. Novel tests were conducted in this research, which used ion-exchange resin beads (IERB) to replace nonconductive spacer fabrics in RED compartments with dilute NaCl solution in a modified stack containing Fumasep FKS and Fumasep FAS membranes. We compared the conductivity of an IERB packed bed with that of an inert glass-beads-packed bed as a control to confirm IERB's effectiveness. When applied in a RED system, IERB decreased the stack resistance by up to 40%. The maximum gross power density improved by 83% in the RED stack compared to that in a regular RED stack at 1.3 cm/s average linear flow velocity. IERB-filled stack resistance was modeled. The model results fit well with experimental data, thereby confirming the effectiveness of the new approach presented here. The net power density is also estimated based on the measured pressure drop and pumping energy model. Both gross and net power density was improved by over 75% at higher flow rate. A net power density of 0.44 W/m(2) was achieved at a cell thickness of 500 μm. To the best of our knowledge, this research is the first to study the impact of IERB on power generation and establishes a new approach to improving the power performance of a RED system.

UI MeSH Term Description Entries
D007475 Ion Exchange Resins High molecular weight, insoluble polymers which contain functional groups that are capable of undergoing exchange reactions (ION EXCHANGE) with either cations or anions. Ion Exchange Resin,Exchange Resin, Ion,Exchange Resins, Ion,Resin, Ion Exchange,Resins, Ion Exchange
D007477 Ions An atom or group of atoms that have a positive or negative electric charge due to a gain (negative charge) or loss (positive charge) of one or more electrons. Atoms with a positive charge are known as CATIONS; those with a negative charge are ANIONS.
D008567 Membranes, Artificial Artificially produced membranes, such as semipermeable membranes used in artificial kidney dialysis (RENAL DIALYSIS), monomolecular and bimolecular membranes used as models to simulate biological CELL MEMBRANES. These membranes are also used in the process of GUIDED TISSUE REGENERATION. Artificial Membranes,Artificial Membrane,Membrane, Artificial
D004563 Electrochemistry The study of chemical changes resulting from electrical action and electrical activity resulting from chemical changes. Electrochemistries
D004867 Equipment Design Methods and patterns of fabricating machines and related hardware. Design, Equipment,Device Design,Medical Device Design,Design, Medical Device,Designs, Medical Device,Device Design, Medical,Device Designs, Medical,Medical Device Designs,Design, Device,Designs, Device,Designs, Equipment,Device Designs,Equipment Designs
D005618 Fresh Water Water containing no significant amounts of salts, such as water from RIVERS and LAKES. Freshwater,Fresh Waters,Freshwaters,Water, Fresh,Waters, Fresh
D012623 Seawater The salinated water of OCEANS AND SEAS that provides habitat for marine organisms. Sea Water,Sea Waters,Seawaters,Water, Sea,Waters, Sea
D012965 Sodium Chloride A ubiquitous sodium salt that is commonly used to season food. Sodium Chloride, (22)Na,Sodium Chloride, (24)NaCl
D012996 Solutions The homogeneous mixtures formed by the mixing of a solid, liquid, or gaseous substance (solute) with a liquid (the solvent), from which the dissolved substances can be recovered by physical processes. (From Grant & Hackh's Chemical Dictionary, 5th ed) Solution
D014872 Water Movements The flow of water in enviromental bodies of water such as rivers, oceans, water supplies, aquariums, etc. It includes currents, tides, and waves. Movement, Water,Movements, Water,Water Movement

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