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Zinc(II)-Mediated Carbene Insertion into C-H Bonds in Alkanes. 2015
Naveen V Kulkarni, and
Chandrakanta Dash, and
Naleen B Jayaratna, and
Shawn G Ridlen, and
Sarah Karbalaei Khani, and
Animesh Das, and
Xiaodi Kou, and
Muhammed Yousufuddin, and
Thomas R Cundari, and
H V Rasika Dias
Department of Chemistry and Biochemistry, The University of Texas at Arlington , Arlington, Texas 76019, United States.
The cationic zinc adduct {[HB(3,5-(CF3)2Pz)3]Zn(NCMe)2}ClO4 catalyzes the functionalization of tertiary, secondary, and primary C-H bonds of alkanes via carbene insertion. Ethyl diazoacetate serves as the :CHCO2Et carbene precursor. The counteranion, supporting ligand, and coordinating solvents affect the catalytic activity. An in situ generated {[HB(3,5-(CF3)2Pz)3]Zn}(+) species containing a bulkier {B[3,5-(CF3)2C6H3]4}(-) anion gives the best results among the zinc catalysts used.
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