Distribution, compositional pattern and sources of polycyclic aromatic hydrocarbons in urban soils of an industrial city, Lanzhou, China. 2016

Yufeng Jiang, and Uwamungu J Yves, and Hang Sun, and Xuefei Hu, and Huiying Zhan, and Yingqin Wu
School of Environmental & Municipal Engineering, Lanzhou Jiaotong University, Lanzhou 730070, PR China. Electronic address: Jiangyf7712@126.com.

The level, distribution, compositional pattern and possible sources of polycyclic aromatic hydrocarbons (PAHs) in Lanzhou urban soil of Northwest China were investigated in this study. The total level of 22 PAHs ranged from 115 to 12,100 µg kg(-1) and that of 16 priority PAHs from 82.4 to 10,900 µg kg(-1). Seven carcinogenic PAHs generally accounted for 6.18-57.4% of total 22 PAHs. Compared with data from those reported about urban areas, PAH contamination in Lanzhou urban soils was moderate. Among different functional areas, higher level of PAHs was found along roadsides and in the industrial district (p<0.01), while lower levels were detected in the commercial, park and residential districts. The composition of PAHs was characterized by high molecular weight PAHs (≥4 rings), among which fluoranthene, benz[a]anthracene and phenanthrene were the most dominant components. Correlation analysis suggested that low molecular weight PAHs and high molecular weight PAHs originated from different sources and further corroborated that TOC was an important factor in the accumulation of PAHs in soil. Isomer ratios and principal component analysis indicated that PAHs in urban soil derived primarily from emissions resulting from the combustion of biomass, coal and petroleum products. Toxic equivalent concentrations (BaP(eq)) of soil PAHs ranged from 6.12 to 1302 µg BaP(eq) kg(-1), with a mean of 138 µg BaP(eq) kg(-1). The results suggested that human exposure to those soils which polluted by high concentrations of PAHs through direct ingestion or inhalation of suspended soil particles probably poses a significant risk to human health from the carcinogenic effects of PAHs.

UI MeSH Term Description Entries
D007220 Industrial Waste Worthless, damaged, defective, superfluous or effluent material from industrial operations. Waste, Industrial,Industrial Wastes,Wastes, Industrial
D011084 Polycyclic Aromatic Hydrocarbons Aromatic hydrocarbons that contain extended fused-ring structures. Polycyclic Aromatic Hydrocarbon,Polycyclic Hydrocarbons, Aromatic,Polynuclear Aromatic Hydrocarbon,Polynuclear Aromatic Hydrocarbons,Aromatic Hydrocarbon, Polycyclic,Aromatic Hydrocarbon, Polynuclear,Aromatic Hydrocarbons, Polycyclic,Aromatic Hydrocarbons, Polynuclear,Aromatic Polycyclic Hydrocarbons,Hydrocarbon, Polycyclic Aromatic,Hydrocarbon, Polynuclear Aromatic,Hydrocarbons, Aromatic Polycyclic,Hydrocarbons, Polycyclic Aromatic,Hydrocarbons, Polynuclear Aromatic
D002681 China A country spanning from central Asia to the Pacific Ocean. Inner Mongolia,Manchuria,People's Republic of China,Sinkiang,Mainland China
D002947 Cities A large or important municipality of a country, usually a major metropolitan center. Municipalities,Towns
D003031 Coal A natural fuel formed by partial decomposition of vegetable matter under certain environmental conditions. Anthracite,Bituminous Coal,Brown Coal,Lignite,Lignitious Coal,Peat Coal,Soft Coal,Anthracites,Bituminous Coals,Brown Coals,Coal, Bituminous,Coal, Brown,Coal, Lignitious,Coal, Peat,Coal, Soft,Coals,Coals, Bituminous,Coals, Brown,Coals, Lignitious,Coals, Peat,Coals, Soft,Lignites,Lignitious Coals,Peat Coals,Soft Coals
D006801 Humans Members of the species Homo sapiens. Homo sapiens,Man (Taxonomy),Human,Man, Modern,Modern Man
D012987 Soil The unconsolidated mineral or organic matter on the surface of the earth that serves as a natural medium for the growth of land plants. Peat,Humus,Soils
D012989 Soil Pollutants Substances which pollute the soil. Use for soil pollutants in general or for which there is no specific heading. Soil Pollutant,Pollutant, Soil,Pollutants, Soil
D025341 Principal Component Analysis Mathematical procedure that transforms a number of possibly correlated variables into a smaller number of uncorrelated variables called principal components. Analyses, Principal Component,Analysis, Principal Component,Principal Component Analyses

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